Table 1 Thermodynamic parameters and binding constants

From: Cramming versus threading of long amphiphilic oligomers into a polyaromatic capsule

Entry

ΔH (kJ mol–1)

TΔS (kJ mol–1)

ΔG (kJ mol–1)

K a

1•5EO

− 52.76 ± 0.32

− 16.58

− 36.18

(2.13 ± 0.22) × 106 M−1

1•CE

− 47.91 ± 0.51

− 11.60

− 36.31

(2.29 ± 0.43) × 106 M−1

1•10EO

− 59.50 ± 0.18

− 25.06

− 34.44

(1.06 ± 0.04) × 106 M−1

(1)2•OEO1000

− 131.29 ± 0.34

− 99.62

− 31.67

(3.39 ± 0.06) × 105 M−2

  1. Thermodynamic parameters (ΔH and TΔS) and binding constants (Ka) for the formation of 1•5EO, 1•CE, 1•10EO, and (1)2•OEO1000 obtained by ITC experiments (H2O, 298 K)
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