Fig. 4

Schematic of proposed mechanism of surface oxygen interaction. LaMnO3-SrMnO3-LaMnO3 (LSL) interacts with oxygen by adsorbing oxygen atoms without significantly changing surface structure. SrMnO3-LaMnO3-LaMnO3 (SLL) interaction with oxygen involves migration of the A-site Sr atoms to the surface to form Sr-O like bonds