Table 1 Structural information of the existing and designed COFs in our database

From: Materials genomics methods for high-throughput construction of COFs and targeted synthesis

Categories of COFs

Combination waya

Linkageb

Topology

Examplec

2D

Existing COFs

C3 + C2, C2 + C2

(3,2)

hcb

COF-LZU136, COF-134

C3 + C3

(3,3)

hcb

COF-635

C4 + C2

(4,2)

sql, kgm, fxt

Pc-PBBA-COF43, 4PE-1P44, TP-COF-BZ45

C4 + C4

(4,4)

sql, bex, fes

POR-COF46, SIOC-COF-547, ICOF-148

C6 + C2

(6,2)

hxl

HPB-COF49

C6 + C3

(6,3)

kgd

HAT-NTBA-COF50

Designed COFs

C4 + C4

(4,4)

mcm

GCOF-BP

C6 + C4

(6,4)

tth

GCOF-HT

3D

Existing COFs

C3 + C3

(3,3)

srs

SiCOF-551

C4 + C3

(4,3)

ctn, bor

COF-10252, COF-10852

C4 + C2

(4,2)

dia

COF-30030

C4 + C4

(4,4)

pts

3D-Py-COF53

C12 + C4

(12,4)

rra

CD-COFs54

Designed COFs

C4 + C2

(4,2)

sod

GCOF-MT

C4 + C2

(4,2)

cds

GCOF-SB

C4 + C3

(4,3)

ffc

3D-ETTA-TFPA

C6 + C2

(6,2)

pcu

GCOF-HB

C4 + C4

(4,4)

cda

GCOF-ST

C6 + C2

(6,2)

acs

GCOF-TT

C8 + C2

(8,2)

bcu

GCOF-OD

C12 + C3

(12,3)

ttt

GCOF-DH

  1. aPossible combination ways of reaction substrates, where Cn means the substrates with n reactive terminals
  2. bThe linkage can be inferred from the combination way of reaction substrates. For instance, the (3,2) linkage can be realized by the co-condensation of C3 + C2 or the self-condensation of C2
  3. cThe representatives of the designed COFs are shown in Supplementary Fig. 7
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