Table 1 Crystallographic parameters, XB distances, angles, RXB and RI>2σ for (tftib)(PPh3), (tftib)(AsPh3) and (tftib)(SbPh3), determined at 103 K
From: Halogen-bonded cocrystallization with phosphorus, arsenic and antimony acceptors
(tftib)(PPh3) | (tftib)(AsPh3) | (tftib)(SbPh3) | |
|---|---|---|---|
a (Å) | 9.1186(8) | 9.1477(8) | 9.1863(10) |
b (Å) | 10.8976(10) | 11.0051(9) | 11.2726(12) |
c (Å) | 13.3301(12) | 13.3755(12) | 13.3561(14) |
α (°) | 88.147(3) | 88.515(3) | 89.190(4) |
β (°) | 72.738(3) | 71.685(3) | 70.066(4) |
γ (°) | 76.213(3) | 76.816(3) | 78.455(4) |
dXB,exp (Å) | 3.3133(5) | 3.4211(3) | 3.5747(3) |
R XB | 0.877 | 0.893 | 0.885 |
∠C−I···E (o) | 165.33(4) | 166.02(5) | 168.28(6) |
RI>2σ (%) | 2.66 | 3.13 | 3.12 |
