Table 1 Substrate scope of the reaction protocola

From: Lithium promoted mesoporous manganese oxide catalyzed oxidation of allyl ethers

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  1. aReaction condition: substrate (2 mmol), Temp- 80 °C, solvent- 2.5 mL, Catalyst- meso-Li-Mn2O3 (25 mg), NHPI (25 mol%), 6 h and air balloon. bBond dissociation energies (BDE) were calculated by DFT using CBS–QB3 basis set. Numbers in parenthesis are the isolated yields. cConversions and selectivities were determined by GC-MS (in all cases >99% selectivity were obtained). dYield = Conversion × selectivity (%), eTOF = TON/h, TON = mole of ether converted to the product over mole of catalyst used. f8 h, g16 h
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