Table 1 Types of [4]12-catenanes formed in terms of the first amino acid residue in the tripeptide ligand sequence

From: Metal–peptide rings form highly entangled topologically inequivalent frameworks with the same ring- and crossing-numbers

Ligand

Peptide sequence

Peptide conformation

[4]12-Catenane type

1

–P–G–P–

Ω-shaped loop

T2-tetrahedral link

3

–T–P–P–

PII-helix

Three-crossed tetrahedral link

5

–A–P–P–

PII-helix

Three-crossed tetrahedral link

7

–I–P–P–

Ω-shaped loop

T2-tetrahedral link

9

–V–P–P–

Ω-shaped loop

T2-tetrahedral link