Fig. 2
From: Unusual substrate and halide versatility of phenolic halogenase PltM
Halogenation of phloroglucinol (1) by PltM. a XIC traces showing the homo-halogenation of 1 by PltM with NaCl (left), NaBr (middle), and NaI (right) as halide sources. Blue and pink traces depict mono-halogenation and dihalogenation, respectively. b Halogenation of 1 by PltM with equimolar ratio of NaCl/NaBr (left), NaCl/NaI (middle), and NaBr/NaI (right). Blue and green traces show mono-halogenation with smaller and larger halogens, respectively; while purple trace indicates dehalogenation. c Halogenation of 1 by PltM with NaCl/NaI (left) and NaBr/NaI (right) in a 10:1 ratio. Blue and green traces show mono-halogenation with smaller and larger halogens, respectively; while purple and pink traces indicate homo-dihalogenation with smaller and larger halogens, respectively. The brown trace displays hetero-dihalogenated products. The orange trace shows the unreacted substrate 1
