Fig. 1
From: Nickel-catalysed selective migratory hydrothiolation of alkenes and alkynes with thiols

Design of a NiH-catalyzed remote hydrothiolation reaction. a Representative organosulfur compounds in natural products and pharmaceuticals. b Previous work: remote hydrofunctionalization of alkenes with electrophilic coupling reagents. c This work: selective migratory hydrothiolation of unactivated alkenes/alkynes with thiols directly. tBu, tert-butyl; Ph, phenyl; FG, functional group; LG, leaving group