Table 2 Scope of radical α-borylation of β-aryl-α,β-unsaturated carbonyl compounds

From: Regioselective radical α-borylation of α,β-unsaturated carbonyl compounds for direct synthesis of α-borylcarbonyl molecules

  1. aStandard conditions: 2a (0.2–0.3 mmol), 1 (1.2 equiv), AIBN (20 mol%), tert-dodecanethiol (50 mol%), CH3CN (2 ml), 80 °C for 12 h
  2. bPhSH (20 mol%) was used
  3. cThe structures of 3f, 3p-β, 3u’, and 3aa were secured by X-ray crystallographic analysis
  4. dIsolated yield of a gram-scale synthesis
  5. eIsooctyl thioglycolate (20 mol%) was used
Back to article page