Fig. 10
From: Visualization and design of the functional group distribution during statistical copolymerization
Generic nature of concept of functionality-chain length distributioons. a, b case of synthesis of functional copoly(2-oxazoline) at 100% monomer conversion for target DP of a 100 and b 400 (optimized conditions from Fig. 9). c, d case of atom transfer radical polymerization (ATRP) of c styrene and N-propyl maleimide; and d ethylhexyl acrylate and glycidyl methacrylate (monomer conversion of 90%); conditions for (c): target DP of 100; [styrene]0:[R0X]0:[Activator]0: 100:1:1; 110 °C; addition of 1 eq. of N-propyl maleimide at 35% styrene conversion with respect to ATRP initiator R0X; conditions for (d): target DP of 100; [M]0:[R0X]0: [Activator]0: 100:1:1; 10 mol % of glycidyl methacrylate at start; solvent toluene; 70 °C31,32
