Fig. 1 | Nature Communications

Fig. 1

From: Intramolecular substitutions of secondary and tertiary alcohols with chirality transfer by an iron(III) catalyst

Fig. 1

Substitution of the OH groups of enantioenriched alcohols with chirality transfer. a, b, Gold-catalyzed and palladium-catalyzed SN2′-type allylic amination and etherification reactions. c Phosphinic acid-catalyzed SN2-type intramolecular substitution of the OH groups of secondary alcohols. d Stereoinversion of tertiary alcohols by tertiary-alkyl isonitriles. e Iron-catalyzed intramolecular substitution with chirality transfer of the OH groups of enantioenriched secondary and tertiary alcohols

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