Table 2 Comparison of the catalytic performance for NH3 decomposition of different catalysts

From: Highly efficient decomposition of ammonia using high-entropy alloy catalysts

Catalysts

Metals

NH3

T

GHSV

Conversion

TOFa

Ref

 

(wt%)

(vol%)

(°C)

(mL gcat−1 h−1)

(%)

(h−1)

 

Ru/SiO2

10

100

500

30,000

64

2283

2

Ru/Al2O3

10

100

500

30,000

58

2069

26

Ru/CNTs

4.8

100

500

30,000

84

6241

5

Ru/TiO2

4.8

100

500

30,000

64

11,096

27

Ru/MgO

5

100

500

30,000

41

8189

24

Co(en)3MoO4

38.8

100

500

36,000

12

294

14

Co3Mo3N

97

50

500

22,500

33

409

12

CoMo/SiO2

5

100

500

36,000

14

1108

47

FeMo/La-Al2O3

10

100

500

46,000

8

1213

48

Ni2Mo3N

97

100

500

21,600

29

204

49

Li2NH-Fe2N

81.2

100

500

60,000

38.1

1179

50

Li2NH-Mn2N

81

100

500

60,000

59.1

2735

50

HEA-Co25Mo45

7.8

5

500

36,000

84

1571

This work

HEA-Co35Mo35

8.3

5

500

36,000

67

1128

This work

HEA-Co45Mo25

8.8

100

500

36,000

64.5

19,633

This work

HEA-Co55Mo15

9.3

100

500

36,000

100

25,209

This work

  1. a Obtained by normalizing the reported reaction rates with the areal densities of surface atoms estimated from the particle sizes