Fig. 6 | Nature Communications

Fig. 6

From: Structural insights into the formation and voltage degradation of lithium- and manganese-rich layered oxides

Fig. 6The alternative text for this image may have been generated using AI.

Two distinct pathways of Li-rich layered oxide formation from Li-free spinel oxide. Schematic diagram of lithium- and oxygen-incorporation-induced structural and electrical evolution during synthesis of layered Li[Li1.2Ni0.2Mn0.6]O2 cathode materials, revealing the formation mechanisms of Mn-rich cathodes during slow (I) and fast (II) thermal treatments, and the possible origin of voltage decay in high-energy lithium-excess layered oxides, i.e., a kind of partially reversed formation pathway (II) of LMLOs under non-equilibrium conditions (lithium extraction accompanying oxygen evolution).

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