Table 3 Heterogeneous visible light oxidative coupling of various amines into iminesa.
From: Elucidating heterogeneous photocatalytic superiority of microporous porphyrin organic cage
| |||||
|---|---|---|---|---|---|
Entry | Substrate | Product | t (min) | Conv. (%)b | TOFc |
1 | R=H | R=H | 60 | >99 | 33.0 |
2 | R=F | R=F | 50 | >99 | 39.6 |
3 | R=CH3 | R=CH3 | 60 | >99 | 33.0 |
4 | R=OCH3 | R=OCH3 | 70 | >99 | 28.2 |
5 | R=Cl | R=Cl | 90 | >99 | 22.0 |
6 |
|
| 50 | >99 | 39.6 |
7 |
|
| 120 | >99 | 16.5 |
8 |
|
| 140 | >99 | 14.1 |
9d | R=H | R=H | 180 | >99 | 11.0 |
10e | R=H | R=H | 120 | >99 | 16.5 |
11f | R=H | R=H | 300 | >99 | 6.6 |
12g | R=H | R=H | 60 | 25 | 8.3 |
13h | R=H | R=H | 60 | 57 | 19.0 |
