Fig. 2: Analysis of the multiple-roles played by the reductant.

a–c TEM images and photographs (insets) of the resulting gold materials for NaBH4/gold ratios of 1/1, 4/1, and 100/1, and d the function(s) of NaBH4 exhibited in the respective systems. e The ligament size of the gold gels vs. the NaBH4/gold ratio (error bars depict the standard deviation). f The peak position at maximum absorption (from UV-vis absorption spectra) vs. the reductant/gold ratio for different reductants. g Theoretically calculated binding energies between the gold atom and various anions. h The proposed mechanisms for the excessive NaBH4-directed gelation process. The scale bars are 50 nm in a–c.