Table 2 Model fluxes.

From: Permo–Triassic boundary carbon and mercury cycling linked to terrestrial ecosystem collapse

Description

Name

Equation

Size at present

Transfer fluxes

\({\mathrm{tran}}_{{\mathrm{ij}}}\)

\({\mathrm{C}}_{\mathrm{i}}{\mathrm{f}}_{{\mathrm{circ}}}\)

Multiple

Air–sea exchanges

\({\mathrm{f}}_{{\mathrm{airsea}}_{\mathrm{j}}}\)

\({\mathrm{A}}_{\mathrm{j}}{\mathrm{M}}_{{\mathrm{atm}}}({\textstyle{{{\mathrm{pCO}}_{2{\mathrm{a}}} - {\mathrm{pCO}}_{2{\mathrm{j}}}} \over {\tau _{{\mathrm{oa}}}}}})\)

Multiple

Silicate weathering

\({\mathrm{f}}_{{\mathrm{silw}}}\)

\({\mathrm{k}}_{{\mathrm{basw}}}{\mathrm{f}}_{{\mathrm{T}}_{{\mathrm{bas}}}} + {\mathrm{k}}_{{\mathrm{granw}}}{\mathrm{f}}_{{\mathrm{T}}_{{\mathrm{gran}}}}\)

\(8 \times 10^{12}\). mol C yr−1

Carbonate weathering

\({\mathrm{f}}_{{\mathrm{carbw}}}\)

\({\mathrm{k}}_{{\mathrm{carbw}}}{\mathrm{f}}_{{\mathrm{Tcarb}}}\)

\(8 \times 10^{12}\) mol C yr−1

Oxidative weathering

\({\mathrm{f}}_{{\mathrm{oxidw}}}\)

\({\mathrm{k}}_{{\mathrm{oxidw}}}\left( {{\mathrm{RO}}_2} \right)^{0.5}{\mathrm{F}}_{{\mathrm{oxidw}}}\)

\(7.75 \times 10^{12}\) mol C yr−1

Carbonate degassing

\({\mathrm{f}}_{{\mathrm{ccdeg}}}\)

\({\mathrm{k}}_{{\mathrm{ccdeg}}}{\mathrm{D}}\)

\(8 \times 10^{12}\) mol C yr−1

Organic carbon degassing

\({\mathrm{f}}_{{\mathrm{ocdeg}}}\)

\({\mathrm{k}}_{{\mathrm{ocdeg}}}{\mathrm{D}}\)

\(1.25 \times 10^{12}\) mol C yr−1

Mare carbonate burial

\({\mathrm{f}}_{{\mathrm{mccb}}}\)

\({\mathrm{k}}_{{\mathrm{mccb}}}{\textstyle{{\left( {{\mathrm{\Omega }} - 1} \right)^{1.7}} \over {{\mathrm{\Omega }}_0}}}\)

\(16 \times 10^{12}\) mol C yr−1

Marine organic C burial

\({\mathrm{f}}_{{\mathrm{mocb}}}\)

\({\mathrm{k}}_{{\mathrm{mocb}}}\)

\(4.5 \times 10^{12}\) mol C yr−1

Marine carbonate burial

\({\mathrm{f}}_{{\mathrm{mccb}}}\)

\({\mathrm{k}}_{{\mathrm{mccb}}}\)

\(16 \times 10^{12}\) mol C yr−1

Land organic C burial

\({\mathrm{f}}_{{\mathrm{locb}}}\)

\({\mathrm{k}}_{{\mathrm{locb}}}{\mathrm{F}}_{{\mathrm{Cburial}}}\)

\(4.5 \times 10^{12}\) mol C yr−1

Volcanic Hg release

\({\mathrm{f}}_{{\mathrm{Hg}}_{\mathrm{volc}}}\)

\({\mathrm{k}}_{{\mathrm{Hg}}_{{\mathrm{volc}}}}{\mathrm{F}}_{{\mathrm{Hg}}_{input}}\)

\(1.5 \times 10^6\) mol Hg yr−1*

Wildfire Hg release

\({\mathrm{f}}_{{\mathrm{Hg}}_{\mathrm{wildfire}}}\)

\({\mathrm{k}}_{{\mathrm{Hg}}_{{\mathrm{wildfire}}}}\)

\(5 \times 10^5\) mol Hg yr−1*

Riverine Hg runoff

\({\mathrm{f}}_{{\mathrm{Hg}}_{\mathrm{runoff}}}\)

\({\mathrm{k}}_{{\mathrm{Hg}}_{{\mathrm{runoff}}}}{\mathrm{F}}_{{\mathrm{runoff}}}\)

\(2 \times 10^6\) mol Hg yr−1*

Marine Hg burial

\({\mathrm{f}}_{{\mathrm{Hg}}_{\mathrm{b}}}\)

\({\mathrm{k}}_{{\mathrm{Hg}}_{\mathrm{b}}}({\textstyle{{{\mathrm{Hg}}_{\mathrm{s}}} \over {{\mathrm{Hg}}_{{\mathrm{s}}_0}}}})\)

\(2 \times 10^6\) mol Hg yr−1*

Vegetation Hg deposition

\({\mathrm{f}}_{{\mathrm{vegdep}}}\)

\({\mathrm{k}}_{{\mathrm{Hg}}_{{\mathrm{vegdep}}}}({\textstyle{{{\mathrm{Hg}}_{\mathrm{a}}} \over {{\mathrm{Hg}}_{{\mathrm{a}}_0}}}})\)

\(1 \times 10^7\) mol Hg yr−1*

Vegetation Hg evasion

\({\mathrm{f}}_{{\mathrm{vegeva}}}\)

\({\mathrm{k}}_{{\mathrm{Hg}}_{{\mathrm{vegeva}}}}\)

\(1 \times 10^7\) mol Hg yr−1*

Ocean Hg deposition

\({\mathrm{f}}_{{\mathrm{oceandep}}_{\mathrm{j}}}\)

\({\mathrm{k}}_{{\mathrm{Hg}}_{{\mathrm{oceandep}}}}({\textstyle{{{\mathrm{Hg}}_{\mathrm{a}}} \over {{\mathrm{Hg}}_{{\mathrm{a}}_0}}}})\)

\(1.5 \times 10^7\) mol Hg yr−1*

Ocean Hg evasion

\({\mathrm{f}}_{{\mathrm{oceaneva}}_{\mathrm{j}}}\)

\({\mathrm{k}}_{{\mathrm{Hg}}_{{\mathrm{oceaneva}}}}({\textstyle{{{\mathrm{Hg}}_{\mathrm{j}}} \over {{\mathrm{Hg}}_{{\mathrm{j}}_0}}}})\)

\(1.5 \times 10^7\) mol Hg yr−1*

  1. *Volcanic Hg flux follows ref. 25, and is assumed equivalent to the total Hg burial in their model to close the system over long timescales. This value is within their stated reasonable range but is ~2× their chosen volcanic flux, the value is further increased by 50% due to higher rates of tectonic degassing through the Permian and Triassic. Runoff and burial fluxes are calculated to close the system under volcanic and wildfire input. Deposition and evasion fluxes directly follow ref. 25.