Table 3 Fixed model parameters.

From: Permo–Triassic boundary carbon and mercury cycling linked to terrestrial ecosystem collapse

Description

Name

Size at present

Thermohaline speed

\({\mathrm{f}}_{{\mathrm{circ}}}\)

10 Sv

Relative area of low-latitude surface ocean

\({\mathrm{A}}_{\mathrm{s}}\)

0.85

Relative area of high-latitude surface ocean

\({\mathrm{A}}_{\mathrm{h}}\)

0.15

Present day moles of atmospheric CO2

\({\mathrm{M}}_{{\mathrm{atm}}}\)

\(5 \times 10^{16}\) mol C

Timescale parameter for gas exchange

\(\tau _{{\mathrm{oa}}}\)

10 years

Long-term climate sensitivity

\({\mathrm{k}}_{{\mathrm{clim}}}\)

5 K

CO2 second dissociation constant

\({\mathrm{K}}_2\)

\(7.4 \times 10^{-10}\)

Calcium carbonate solubility product

\({\mathrm{K}}_{{\mathrm{sp}}}\)

0.8 mmol2 kg−2 *

Present day CaCO3 saturation state

\({\mathrm{\Omega }}_0\)

3

Marine calcium concentration

\([{\mathrm{Ca}}]\)

10 mM

Photosynthetic C fractionation

ΔB

27‰

C-isotope composition of carbonates

\(\delta ^{13}{\mathrm{C}}_{\mathrm{C}}\)

0‰

C isotope composition of organics

\(\delta ^{13}{\mathrm{C}}_{\mathrm{G}}\)

−27‰

  1. *Chosen within ocean range (0.43–1.15)56 to achieve reasonable DIC and ALK at present.