Table 3 Olefin substrate scopea.

From: Pd-catalyzed formal Mizoroki–Heck coupling of unactivated alkyl chlorides

  1. aReaction conditions: 1b–1z (0.1 mmol), 2a (0.15 mmol), Pd(PPh3)4 (5 mol %), K2CO3 (0.2 mmol), and DMA [0.1 M] under 40 W blue LED irradiation with fan cooling (30 ± 5 °C). All yields are isolated yields. E:Z > 20:1.
  2. bE:Z = 1:1.
  3. cE:Z = 1:2.
  4. dWith 0.3 mmol 2a.
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