Table. 4 Synthetic applicationsa.

From: Pd-catalyzed formal Mizoroki–Heck coupling of unactivated alkyl chlorides

  1. aReaction conditions: 1a (0.15 mmol), 2ac–2ag (0.1 mmol) or 1aa–1ac (0.1 mmol), 2a (0.15 mmol), Pd(PPh3)4 (5 mol %), K2CO3 (0.2 mmol), and DMA [0.1 M] under 40 W blue LED irradiation with fan cooling (30 ± 5 °C). All yields are isolated yields.
  2. bd.r. = 3:4.
  3. cd.r. = 2:1.
  4. dPd(PPh3)4 (10 mol %), 48 h.
  5. eE:Z = 1.3:1.
  6. fReaction conditions: 1a (0.2 mmol), 2ah–2al (0.1 mmol), Pd(PPh3)4 (5 mol %), K2CO3 (0.4 mmol), in DMA [0.1 M] under 40 W blue LED irradiation with fan cooling (30 ± 5 °C). All yields are isolated yields.
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