Fig. 4: Scope of seven-membered triorgano-substituted silicon-stereogenic heterocycles.

Reaction conditions: 3 (0.1 mmol), [Rh(cod)Cl]2 (1 mol%), L3 (3 mol%) in toluene (1 mL) at 100 °C for 12 h.

Reaction conditions: 3 (0.1 mmol), [Rh(cod)Cl]2 (1 mol%), L3 (3 mol%) in toluene (1 mL) at 100 °C for 12 h.