Fig. 5: Mechanistic study.

a Effect of TEMPO for carbosilylation of 1a, 3a, and Et3SiBPin. b, c Radical clock experiments. d Effect of TEMPO for the reaction of alkyl fluoride 2k and Et3SiBPin. e Proposed reaction mechanisms.

a Effect of TEMPO for carbosilylation of 1a, 3a, and Et3SiBPin. b, c Radical clock experiments. d Effect of TEMPO for the reaction of alkyl fluoride 2k and Et3SiBPin. e Proposed reaction mechanisms.