Fig. 5: Ultrafast solid-state rotations of a diamondoid molecule in the hybrid nanocarbon peapod of adm⊃[3]CdbC from 2H NMR analyses. | Nature Communications

Fig. 5: Ultrafast solid-state rotations of a diamondoid molecule in the hybrid nanocarbon peapod of adm⊃[3]CdbC from 2H NMR analyses.

From: A hybrid molecular peapod of sp2- and sp3-nanocarbons enabling ultrafast terahertz rotations

Fig. 5

a A high-field shift observed between the spectra of [3]CdbC⊃adm-d16 and free adm-d16 under MAS conditions (298 K). b A symmetric narrow peak of adm-d16 observed with [3]CdbC⊃adm-d16 under static conditions without MAS (298 K). A hypothetical spectrum simulated for motionless adm-d16 is shown at the bottom as a reference to show its absence. c Temperature-dependent rotational frequency (krot) recorded with [3]CdbC⊃adm-d16. The bars show the standard errors of the estimate.

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