Fig. 4: Atomic-scale imaging of the decomposition pathway.
From: Atomic-scale imaging of CH3NH3PbI3 structure and its decomposition pathway

a–d HRTEM images with increased doses during the degradation into PbI2. The corresponding doses are marked on each panel. Scale bar, 2 Å. e Atomic structure of MA0.5PbI3. Black squares indicate \({{{\mbox{V}}}}_{{{\mbox{MA}}}}^{-}\). f Atomic structures to illustrate two kinds of I− and Pb2+ diffusion. Left panel shows I− and Pb2+ diffusing to \({{{\mbox{V}}}}_{{{\mbox{MA}}}}^{-}\) while the right panel illustrates the [PbI6]4− octahedron slipping from corner sharing to edge sharing. g Atomic structure of PbI2.