Fig. 1: Examples of reaction pathways when a PAH molecule (here a coronene cation) is damaged by the knockout of a C atom in a collision with an energetic particle.
From: Survival of polycyclic aromatic hydrocarbon knockout fragments in the interstellar medium

These types of reactions are proposed to take place in the ISM where PAH molecules/ions are abundant. The calculated C23H\({}_{x}^{+}\) structures are from Stockett et al.26. Background image credit: ESO/U. G. Jørgensen.