Table 1 Scope of PEC C−H halogenation over TiO2-Ov-400 photoanode.

From: Photoelectrocatalytic C–H halogenation over an oxygen vacancy-rich TiO2 photoanode

  1. aGeneral conditions: substrate (0.1 mmol) in NaX (0.5 M, 10 mL) at ambient temperature under AM 1.5 G, 100 mW cm−2 illumination, Ar, 10 h. Applied potential, E = 1.6 V vs. RHE, conversion and selectivity. Other products are shown in Supplementary Figs. 24–53.
  2. bGeneral conditions: substrate (0.1 mmol) dissolved in 0.5 mL acetonitrile, NaCl (0.5 M, 10 ml) at ambient temperature under AM 1.5 G, 100 mW cm−2 illumination, Ar, 10 h. Applied potential, E = 1.6 V vs. RHE, conversion and selectivity. Other products are shown in Supplementary Figs. 24–53.
  3. cProducts obtained at low conversion.
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