Fig. 5: Scope with regard to the alcohol in the synthesis of primary anilines.
From: Hydroxylamine-mediated C–C amination via an aza-hock rearrangement
Reaction conditions: alcohol (0.2 mmol), 5 m (0.3 mmol), TFE (trifluoroethanol) (1 mL), 12 h, r.t.; a1a (4 mmol), 5 m (6 mmol), TFE (20 mL); bHFIP (hexafluoroisopropanol) (1 mL) was instead of TFE (1 mL); Ac acetyl, Ts toluenesulfonyl.
