Table 1 Electrochemical data.

From: Creation of an unexpected plane of enhanced covalency in cerium(III) and berkelium(III) terpyridyl complexes

Complex

E1/2 (vs. Fc/Fc+) (V)

Ep,a (vs. Fc/Fc+) (V)

Ep,c (vs. Fc/Fc+) (V)

Ep,a − Ep,c (V)

∆Ep,c for complex vs. non-complexed (V)

Ce1

0.249

1.020

−0.522

1.542

−0.277

Bk1

0.207

−0.158

−0.887

0.729

N/A

  1. All data have been corrected to zero volts vs. an internal Fc/Fc+ reference and was recorded at 100 mV s−1.
Back to article page