Table 2 g-factors for Ce1.

From: Creation of an unexpected plane of enhanced covalency in cerium(III) and berkelium(III) terpyridyl complexes

E (cm−1)

gx

gy

gz

<Lz>

<Sz>

<Lx>

<Sx>

<Ly>

<Sy>

0.0

0.789

1.372

2.671

−1.887

0.275

−0.409

0.007

−0.990

0.152

131.0

0.378

0.969

2.535

−1.708

0.219

−0.254

0.032

−0.601

0.058

299.7

2.640

1.787

0.859

−0.628

0.099

−1.817

0.248

−1.139

0.123

  1. Theoretical energies, g-factors, and the orbital and spin angular momentum expectation values obtained from spin–orbit CAS(1,7) wave functions for the three Kramer’s doublets (KDs) derived from the 2F5/2 ground multiplet.
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