Fig. 2: Profiles of Haojiagou (Upper, HJG) and Qilixia (Lower, QLX) sections.

(a, g) Organic carbon isotope (δ13Corg, ‰); (b, h) Mercury concentrations (Hg, ppb); (c, i) Ratios of mercury to total organic carbon (Hg/TOC, ppb/wt.%); (d, j) Mass independence fractionation of odd-Hg isotope (Δ199Hg, ‰); (e, k) Chemical index of alteration (CIA) and (f, l) clay minerals. The eccentricity cycle and ages are from Sha et al.53 and Li et al.70 for Haojiagou and Qilixia respectively. The red crosses in represent δ13Corg data from Sha et al.53. Open and purple filled circles in c and i represent samples with TOC < 0.2 wt.% and ≥ 0.2 wt.%, respectively. ICW Intense chemical weathering interval; TJT Triassic–Jurassic transition; ME mercury-enriched interval. The red and green bar at the base of column d and j represent the volcanic (V) and terrestrial (T) compositions of Δ199Hg respectively. The arrow for the ICW represents the uncompleted records in the Early Jurassic for QLX. The horizon bars of the Δ199Hg profiles represent standard deviation (2σ) values. Abbreviations: Sy System, St (sub)stage, F formation, B bed, Z sporomorph assemblage zone, Ec. eccentricity cycle, M member, Jur. Jurassic, Het. Hettangian, ZZC Zhenzhuchong, ICIE Initial carbon isotope excursion, MCIE Main carbon isotope excursion, PCIE precursor carbon isotope excursion. Note: full geochemical data are in Supplementary Figs. 2–3. Source data are provided as a Source Data file.