Fig. 10: Proposed mechanism.

Proposed reaction pathway starts from Xantphos•Co-H species to catalyze the hydrosilylation step, followed by the key ligand relay process to generate the OPAQ•Co-H to catalyze the hydrohydrazidation step.

Proposed reaction pathway starts from Xantphos•Co-H species to catalyze the hydrosilylation step, followed by the key ligand relay process to generate the OPAQ•Co-H to catalyze the hydrohydrazidation step.