Fig. 6: Synthesis of heterocyclic, allylic, and aliphatic nitriles.
From: Efficient iron single-atom catalysts for selective ammoxidation of alcohols to nitriles
Reaction conditions: 0.2 mmol alcohol, 20 mg catalyst (3.9 mol% Fe), aq. NH3·H2O (150 mg), 35 °C, 0.1 MPa air, 1.5 mL H2O, isolated yields; #Yields were determined by GC using n-hexadecane as internal standard; †60 °C; §130 °C, 2 MPa air; &140 °C, 3 MPa air.
