Table 2 Variations in the concentration (in ppb) of pyrimidine nucleobases and their related analogs in meteorite extracts and the Murchison soil.

From: Identifying the wide diversity of extraterrestrial purine and pyrimidine nucleobases in carbonaceous meteorites

  

Molecular formula

m/z (M + H+)

Murchison

Tagish Lake

Murray

Murchison soil

  

#1

#2

Weighted average

ref. 29

This study

ref. 29

Cytosine & its isomers

           

Cytosine

C4H5N3O

112.0505

4

4

4

 

5

2

 

 30

Isocytosine

C4H5N3O

112.0505

0.5

1

1

 

1

0.2

 

 0.2

1H-Imidazole-4-carboxamide

C4H5N3O

112.0505

5

3

4

 

1

6

 

 n.d.

Uracil & its isomers

           

Uracil

C4H4N2O2

113.0346

15

1

7

30

n.d.**

n.d.

19

 <138

2-Imidazole

carboxylic acid

C4H4N2O2

113.0346

19

9

13

 

4

14

 

 n.d.

4-Imidazole

carboxylic acid

C4H4N2O2

113.0346

90

54

70

 

19

99

 

 <20

Methyl cytosine

           

5-Methylcytosine

C5H7N3O

126.0662

1

1

1

 

n.d.

1

 

 n.d.

6-Methylisocytosine

C5H7N3O

126.0662

0.2

0.4

0.3

 

n.d.

1

 

 n.d.

5-Methylisocytosine

C5H7N3O

126.0662

0.1

0.1

0.1

 

n.d.

   

Thymine & its isomers

           

Thymine

C5H6N2O2

127.0502

5

1

3

<2

5

n.d.

≤1

 <19

6-Methyluracil

C5H6N2O2

127.0502

4

0.5

2

 

17

0.3

 

 <12

1-Methyluracil

C5H6N2O2

127.0502

1

5

3

 

n.d.

5

  

1-Methyl-1H-imidazole-5-carboxylic acid

C5H6N2O2

127.0502

150

75

107

 

9

100

  

2-Methyl-1H-imidazole-4-carboxylic acid

C5H6N2O2

127.0502

21

11

15

 

9

23

  

4-Methyl-1H-imidazole-5-carboxylic acid

C5H6N2O2

127.0502

26

22

24

 

n.d.

30

  

Others

           

4-Hydroxypyrimidine

C4H4N2O

97.0396

6

2

4

 

10

3

 

 23

2,4-Diaminopyrimidine

C4H6N4

111.0665

1

n.d.

0.2

 

n.d.

0.2

 

 n.d.

5-amino-4-imidazolecarboxamide

C4H6N4O

127.0614*

0.02

***

     

 n.d.

Dihydrouracil

C4H6N2O2

115.0502

51

n.d.

25

 

n.d.

n.d.

 

 n.d.

Nicotinamide

C6H6N2O

123.0553

10

20

16

 

5

65

  

Isonicotinamide

C6H6N2O

123.0553

3

3

3

 

4

6

  

Picolinamide

C6H6N2O

123.0553

1

2

1

 

3

10

  

Nicotinic acid

C6H5NO2

124.0393

91

264

190

 

108

626

  

Isonicotinic acid

C6H5NO2

124.0393

53

216

147

 

118

307

  
   

Total pyrimidines

37

15

24

 

38

13

  
   

Pyrimidines/Purines

0.2

1.4

0.3

 

4.3

0.4

  
  1. *This is the m/z of the negative ion (M-H)- of 5-amino-4-imidazolecarboxamide.
  2. **n.d. not detected.
  3. ***Blank means “not searched for” in the present study, and “not reported” in previous studies.