Table 2 Comparison of this work and emerging technologies for DAC, DOC, and point source capture. CO2 separation work with “th” subscript denotes thermal energy inputs, whereas “e” subscript denotes electrical work input.

From: Low energy carbon capture via electrochemically induced pH swing with electrochemical rebalancing

Method

Purpose

CO2 separation work inputs (kJ molCO2−1)

Current density (mA cm−2)

Alkaline solvent2,9

DAC

264–396tha

N/A

Solid amine sorbents2

DAC

150–211thb

N/A

Amino acid solvents and solid bis-iminoguanidines10

DAC

152–422thc

N/A

Fuel cell concentrator17

DAC

350ed

0.5

Electrochemical alkaline sorbent regeneration31

DAC

374ef

0.5

Processing seawater within a BPMED reactor13

DOC

155eg

3.3

Titrating seawater with BPMED acid/base12

DOC

394eh

100

Traditional amine ab-/desorption4

Point source capture

132–150th

N/A

Amine ad-/desorption with advanced flash stripper32

Point source capture

92thi

N/A

Shell Cansolv6

Point source capture

103th

N/A

Petra Nova33

Point source capture

89thj

N/A

Quinone Direct binding7

Point source capture

56ek

0.5

EMAR8

Point source capture

30–113el

2.7–11.8

This work

0.1 bar capture

61–145e

20–150

 

0.4 mbar capture

121–237e

20 (extrapolated)

  1. aWork input excludes electrical work required to operate air–liquid contactor, pellet reactor, and auxiliary equipment.
  2. bDesorption energy for mid-range scenario; work input excludes electrical work required to operate air contactor fans and desorption vacuum pump.
  3. cEnergy required for bis(iminoguanidine) regeneration.
  4. dHydrogen gas is the energy source; Energy required to operate water cooling system is excluded.
  5. fThe process starts with a bicarbonate/carbonate solution, mimicking a solution saturated with DIC under 0.4 mbar inlet pCO2. The value is the required work for alkaline sorbent solution regeneration.
  6. gWork input excludes costs for ocean water intake, pre-treatment, and pumping.
  7. hEnergy consumption for the best-case acid process; work input excludes electrical work required to operate pumps and chiller.
  8. iThe inlet gas source contains 11.3% CO2, and the exit is 99% CO2.
  9. jThe inlet gas source contains 11% CO2, and the exit is 97% CO2. This energy is calculated using the electrical power cost, excluding 50% used for compression, plus the steam cost associated with the CCS plant. The captured CO2 was offset by the CO2 emission in the CCS plant.
  10. kThe inlet gas source was simulated flue gas with 15% CO2 and 3% O2 in N2, and exit partial pressure was ~0 bar. Note that the energy cost was calculated based on the amount of CO2 absorbed, yet it is not clear that all absorbed CO2 was released.
  11. lEnergy and current density values adopted from Fig. 8a of ref. 8. Simulated flue gas is 15% CO2 in N2.