Fig. 1: Design plan: Synergistic combination of a chain-walking ligand (L) and an asymmetric arylation ligand (L*) to access chiral 1,1-diarylalkanes.
From: Regio- and enantioselective remote hydroarylation using a ligand-relay strategy
a Stereochemistry in remote NiH catalysis is still a challenging issue. b Multiligand-relay catalysis as a solution for asymmetric remote hydrofunctionalization. c Ni-catalysed multiligand-relay catalysis to access chiral 1,1-diarylalkanes.
