Fig. 3: Matrix and η-phase precipitate compositional evolution during stress-corrosion cracking.

a η-phase precipitate composition around the crack tip and very close to the crack compared with reference values from Supplementary Fig. 1c. The composition of η-phase precipitates captured close to the crack, within 1 µm, in another dataset are also added to the analysis. Cu average composition in the η-phase precipitates at the crack tip and close to the crack is also reported, also showing a marked decrease in Cu content with respect to reference values from Supplementary Fig. 1c. The error values reported for Cu correspond to the standard deviation of all measurements; (b) matrix composition around the crack tip and adjacent to the oxidised secondary crack compared with reference values from Supplementary Fig. 1b. Matrix O levels are also displayed at each data point. Please refer to Supplementary Fig. 8b for error values for O measurements. Precipitate-Free Zone (PFZ).