Fig. 1: Strategies for the construction of deuterated stereocenters. | Nature Communications

Fig. 1: Strategies for the construction of deuterated stereocenters.

From: Visible-light mediated catalytic asymmetric radical deuteration at non-benzylic positions

Fig. 1

a Catalytic asymmetric deuteration via a closed-shell mechanism involving formal deuteride (D–) or deuteron (D+) or via an open-shell deuterium atom transfer (DAT) pathway. b This work, enantioselective deuterofunctionalization of olefins using a chiral thiol catalyst and deuterium oxide (D2O). PC photocatalyst, LED light-emitting diode.

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