Fig. 5: Selective oxidation of methanol catalyzed by MIL-100 (Fe) nanoarrays.
From: Soft nanobrush-directed multifunctional MOF nanoarrays
a Schematic illustration of the catalytic environment of a MIL-100 (Fe) nanoarray and a layer of MIL-100 (Fe) powder. b, c Temperature dependence of conversion (b) and FA selectivity (c) at 160 °C for the oxidation of methanol in the presence of the pristine MIL-100 (Fe) powder, MIL-100 (Fe) powder immobilized on a silicon wafer, soft nanobrushes and MIL-100 (Fe) nanoarrays (2 µL, 6 µL, 16 µL), respectively. d Schematic illustration of the synergistic catalytic effect between the MIL-100 (Fe) nanoarray and MPAV2 during the oxidation of methanol. e, f Temperature dependence of conversion (e) and FA selectivity (f) at 160 °C for the oxidation of methanol in the presence of the MPAV2 (21.5 wt%)-doped MIL-100 (Fe) nanoarray (16 µL), MIL-100 (Fe) nanoarray (16 µL), MPAV2 nanoarray, MPAV2 powder, MPAV2 (11.1 wt%)-doped MIL-100 (Fe) nanoarray (16 µL) and MPAV2 (71.0 wt%)-doped MIL-100 (Fe) nanoarray (16 µL), respectively. Note: DMM = dimethoxymethane, DME = dimethyl ether. Source data are provided as a Source Data file.
