Fig. 3: The scope of chlorosilanes.

Reaction conditions: 1a (0.4 mmol), 2a (0.6 mmol), 3 (1.2 mmol), Ni(PPh₃)₂Cl₂ (10 mol%), L4 (20 mol%), Zn (1.2 mmol), DMA (2 mL), 35 °C, 36 h, N₂ atmosphere. Isolated yield was shown. ^bThe reaction run for 72 h. ^cThe reaction run at 50 °C. d.r. diastereomeric ratio.