Table 1 Summary of maximum gas capacities (\({{n}}_{{{\rm {ads}}}}^{{ {{\max }}}}\)), specific micropore volumes (Vpore) and BET areas (SBET) obtained from the CO2 gas physisorption isotherms collected at 195 K together with the calculated densities (\({{{{{\boldsymbol{\rho }}}}}}\)) for all investigated materials
From: Quantification of gas-accessible microporosity in metal-organic framework glasses
Compound | \({n}_{{{{{{\rm{ads}}}}}}}^{{{\max }}}\,[{\rm {mmol}}\,{\rm {g}}^{-1}]\) | \(V_{{{\rm{pore}}}}[{{{\rm{cm}}}}^{3}\,{{{\rm{g}}}}^{-1}]\) | \(S_{{{\rm{BET}}}}[{{{\rm{m}}}}^{2}\,{{{\rm{g}}}}^{-1}]\) | \(\rho\,[{\rm {g}}\,{\rm {cm}}^{-3}]\) |
|---|---|---|---|---|
ZIF-4 | 7.22 | 0.25 | 490 | 1.22a |
aTZIF-4 | 2.49 | 0.09 | 145 | 1.39b |
zniTZIF-4 | 1.23 | 0.04 | 92 | 1.54a |
agZIF-4 | 2.84 | 0.10 | 187 | 1.38b |
ZIF-zni | 1.21 | 0.04 | 94 | 1.54a |
agZIF-zni | 3.12 | 0.11 | 189 | 1.36b |
ZIF-62 | 4.70 | 0.16 | 264 | 1.29a |
agZIF-62 | 3.34 | 0.12 | 200 | 1.35b |
TIF-4 | 3.76 | 0.13 | 185 | 1.32a |
agTIF-4 | 3.40 | 0.12 | 204 | 1.35b |
