Table 1 Emulsion-based interfacial catalysis

From: General approach to surface-accessible plasmonic Pickering emulsions for SERS sensing and interfacial catalysis

Emulsion-based catalyst

Material (wt%)

Catalyst (wt%)

n (mmol)

C (mM)

T (min)

k (s−1)

CVR (%)

Ref.

AgNP-JMP

1.3

2.6 × 10−2

2.25 × 10-4

/

30

/

97

56

ANPLAg

0.25

1.8 × 10−2

2.25 × 10−4

/

4

/

100

57

m-MOP/Ag@polyHIPE

1

1.6 × 10−2

5 × 10−4

0.05

40

6.17 × 10−4

/

58

J-AuNPs

0.02

8.8 × 10−3

8 × 10−5

0.1

10

/

100

59

Ni-HPF

1

/

5 × 10−3

0.1

24

2.58 × 10−3

>90

60

SiO2NP-AgNP

0.063

1.4 × 10−3

8 × 10−4

0.1

15

2.58 × 10−3

92

This work

  1. Comparison of catalytic performance and experimental parameters of Ag NPs on amphiphilic Janus microparticles (AgNP-JMP)56, amphiphilic nanoplatelets (ANPL) modified with Ag NPs57, Ag-incorporated microporous organic polymer (m-MOP/Ag) particles stabilized high internal phase emulsion (HIPE)58, Janus particles modified with AuNPs (J-AuNPs)59, Nickel-coated hyperporous polymer foam (Ni-HPF)60, and SiO2NP-AgNP Pickering emulsions. The material content (Material) is defined as the weight percentage of the whole material in the aqueous catalytic system. The catalyst content (Catalyst) is defined as the weight percentage of the catalytically active material in the aqueous catalytic system. Quantities that were undetermined are labeled as “/”. The abbreviations “n”, “C”, “T”, “k” and “CVR” corresponds to the amount of 4-nitrophenol, the concentration of 4-nitrophenol, the reaction time, the rate constant and the conversion rate, respectively.
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