Fig. 2: Structural characterisation.

a Raman spectra and b high-resolution W4f XPS spectra of WO3, def-WO3 and Cu0.029-def-WO3. c HRTEM and d aberration corrected HAADF-STEM images of Cu0.029-def-WO3. e x–y line scan curve measured along the yellow rectangle region marked in d. f The optimised configuration of the atomic Cu at A site of def-WO3 over the (002) surface in the top view.