Fig. 3: Pd-catalyzed hydrochlorocarbonylation of various alkenes. | Nature Communications

Fig. 3: Pd-catalyzed hydrochlorocarbonylation of various alkenes.

From: Palladium-catalyzed regiodivergent hydrochlorocarbonylation of alkenes for formation of acid chlorides

Fig. 3

Conditions: alkene (0.2 mmol), PdCl2 (5 mol%), Xantphos (6 mol%), Ph2tBuSiCl (0.3 mmol), AcOH (0.3 mmol), CO (40 atm), PhCl (1.5 mL), 100 °C, 24 h. Isolated yields of the derivatized products (see SI). The ratio of isomers within parentheses was determined by GC-MS analysis of the derivatized products of the acid chlorides.

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