Fig. 7: Preliminary examples of cis-3,6-disubstituted cyclohexene complexes prepared from an η2-allyl complex and various nucleophiles. | Nature Communications

Fig. 7: Preliminary examples of cis-3,6-disubstituted cyclohexene complexes prepared from an η2-allyl complex and various nucleophiles.

From: The double protonation of dihapto-coordinated benzene complexes enables dearomatization using aromatic nucleophiles

Fig. 7: Preliminary examples of cis-3,6-disubstituted cyclohexene complexes prepared from an η2-allyl complex and various nucleophiles.The alternative text for this image may have been generated using AI.

Nucleophilic reagents include TMSCF3 (29D), trimethylsilylacetylene/BuLi (30D), BnMgCl (32D), methyl trimethylsilyl dimethylketene acetal (31D), morpholine (33D), and MeOH/KOH (34D).

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