Fig. 1: Synthesis and characterization of core-shell Au@Pd nanoparticles.

a Visual illustration and b TEM images of the three different studied NPs. Scale bars: 100 nm. The inset shows an EDX with the spatial distribution of the two metals. Au is shown in magenta and Pd in cyan. c Size distributions. Medians are indicated with a black line and displayed on the labels. Sample sizes are N > 60 in all cases. d Calculated absorption cross-sections in water. e Experimental extinction spectra of the colloids. Each spectrum is normalized using its own maximum. Blue, orange, and green correspond to Au67 NS, Au67@Pd2, and Au67@Pd4, respectively. Source data are provided as a Source Data file.