Fig. 8: Investigations involving tricyclic substrates. | Nature Communications

Fig. 8: Investigations involving tricyclic substrates.

From: Discovery of extended product structural space of the fungal dioxygenase AsqJ

Fig. 8

a Synthesis of tricyclic substrates 54/55. b Enzymatic conversion. c Synthesis of hypothesized aldehyde 76 and comparison with isolated compound 74. Green colour indicates same chemical formulas and hence m/z ratios of these compounds. d Synthesis and conversion of l-4-hydroxyproline-derived substrate 69. NMR nuclear magnetic resonance, TBS tert-butyldimethylsilyl.

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