Fig. 1: Diversity-oriented synthesis of structurally diverse monodentate biaryl phosphines containing both P- and axial chirality. | Nature Communications

Fig. 1: Diversity-oriented synthesis of structurally diverse monodentate biaryl phosphines containing both P- and axial chirality.

From: Diversity-oriented synthesis of P-stereogenic and axially chiral monodentate biaryl phosphines enabled by C-P bond cleavage

Fig. 1

a Monodentate biaryl phosphines with various chiral elements. b Transition-metal catalyzed achiral alkynylation of the C–P bond. c Enantioselective C–P bond arylation (our previous work). d Diversity-oriented synthesis of structurally diverse P- and axially chiral monodentate biaryl phosphines (this work).

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