Fig. 3: Mechanistic studies. | Nature Communications

Fig. 3: Mechanistic studies.

From: Construction of C-B axial chirality via dynamic kinetic asymmetric cross-coupling mediated by tetracoordinate boron

Fig. 3

a Yields and ee values of product 3a (recovered 1a) at different reaction times. b Ee values of recovered 1a at different reaction times by using ligands L5 and (-)-L5. c Racemization experiment under standard conditions without aryl trifluoroborates. d Free energy profile calculated for the racemization process with L5 as ligand.

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