Fig. 3: Substrate scope of α-C–C bond cleavage.

Reaction Conditions: 2 (0.1 mmol), Ag3PO4 (0.02 mmol), TEBA (0.2 mmol) and nucleophile (0.3 mmol) in CHCl3 (2.0 mL) at 100 °С for 24 h. Isolated yields are provided. TEBA: Benzyltriethylammonium chloride.