Table 2 Device characteristics of the vacuum-deposited OLEDs based on the TADF compounds doped in DPEPO

From: Enhancing operational stability of OLEDs based on subatomic modified thermally activated delayed fluorescence compounds

Compound

Conc. (wt%)

Vona (V)

Lmaxb (cd m−2)

λmaxc (nm)

CIEd (x, y)

EQEmax/100/1000e (%)

Δroll-offf (%)

CEg (cd A−1)

PEh (lm W−1)

DPA-BO

5

4.4

106

443

0.15, 0.08

11.6/1.3/-

88

5.3

3.7

 

10

3.7

282

449

0.15, 0.09

13.4/4.1/-

70

8.0

5.9

 

15

3.5

629

453

0.14, 0.11

16.5/6.2/-

54

12.4

11.1

 

20

3.3

1361

454

0.14, 0.12

17.1/7.0/1.7

60

14.6

13.5

d-DPA-BO

5

4.1

138

439

0.16, 0.08

13.1/1.9/-

85

7.3

5.5

 

10

3.6

342

446

0.15, 0.09

15.5/3.7/-

74

11.1

9.8

 

15

3.3

890

450

0.15, 0.10

15.1/5.6/-

63

13.6

12.7

 

20

3.2

1511

454

0.14, 0.11

14.6/6.1/2.1

59

14.0

13.7

DPA-d-BO

5

3.9

153

443

0.15, 0.08

12.4/3.2/-

76

4.2

2.8

 

10

3.4

451

449

0.14, 0.09

14.1/5.9/-

60

6.8

5.0

 

15

3.2

1111

450

0.14, 0.10

15.6/7.8/2.4

50

9.3

8.2

 

20

3.2

1672

453

0.14, 0.11

14.8/8.6/3.5

42

9.4

7.6

d-DPA-d-BO

5

4.0

156

443

0.16, 0.07

13.5/2.1/-

85

7.2

5.4

 

10

3.6

456

446

0.15, 0.09

15.4/4.3/-

77

11.3

9.9

 

15

3.3

895

450

0.15, 0.10

16.3/6.0/-

64

14.8

13.8

 

20

3.2

1758

454

0.15, 0.11

12.6/6.5/2.3

49

12.6

12.1

  1. aVon represents turn-on voltage.
  2. bLmax represents maximum luminance.
  3. cλmax represents peak maximum.
  4. dCIE coordinates are taken at luminance of 100 cd m−2.
  5. eEQEmax represents maximum external quantum efficiency.
  6. fEfficiency roll-off measured by ∆roll-off = 1 − (EQE100/EQEmax).
  7. gCE represents maximum current efficiency.
  8. hPE represents maximum power efficiency.