Fig. 2: Scope of the electrochemical halogen-atom transfer (e-XAT) alkylation.

Reaction conditions: RVC anode, Pt cathode, alkyl iodides (0.3 mmol), CH3CN (4.5 mL), H2O (0.45 mL), N2, 3.0 mA, 10 F/mol, 50 oC, 28 h. a48 h, 18 F/mol. Isolated yields.

Reaction conditions: RVC anode, Pt cathode, alkyl iodides (0.3 mmol), CH3CN (4.5 mL), H2O (0.45 mL), N2, 3.0 mA, 10 F/mol, 50 oC, 28 h. a48 h, 18 F/mol. Isolated yields.